MindMap Gallery Chapter 13 Sugar
"Organic Chemistry" final review mind map, with clear context and comprehensive content, is a good helper for review. Welcome to use it! The other chapters are on the homepage. It’s not easy to make. Please give it a like! 🥰
Edited at 2023-10-24 10:53:25This is a mind map about bacteria, and its main contents include: overview, morphology, types, structure, reproduction, distribution, application, and expansion. The summary is comprehensive and meticulous, suitable as review materials.
This is a mind map about plant asexual reproduction, and its main contents include: concept, spore reproduction, vegetative reproduction, tissue culture, and buds. The summary is comprehensive and meticulous, suitable as review materials.
This is a mind map about the reproductive development of animals, and its main contents include: insects, frogs, birds, sexual reproduction, and asexual reproduction. The summary is comprehensive and meticulous, suitable as review materials.
This is a mind map about bacteria, and its main contents include: overview, morphology, types, structure, reproduction, distribution, application, and expansion. The summary is comprehensive and meticulous, suitable as review materials.
This is a mind map about plant asexual reproduction, and its main contents include: concept, spore reproduction, vegetative reproduction, tissue culture, and buds. The summary is comprehensive and meticulous, suitable as review materials.
This is a mind map about the reproductive development of animals, and its main contents include: insects, frogs, birds, sexual reproduction, and asexual reproduction. The summary is comprehensive and meticulous, suitable as review materials.
Chapter 13 Sugar
Monosaccharide
Classification
glucose
pentahydroxyaldehyde
fructose
pentahydroxyketone
Mannose
structure
"right left right right"
glucose
Metarotation phenomenon 242
D/L
Look at the one with the highest number - OH is D on the right
The hemiacetal hydroxyl group is α-type on the same side as the hydroxyl group that determines the configuration, and β-type is on the opposite side.
Epimerism: Only one chiral carbon has a different configuration
Number of optical isomers n is the number of chiral carbons
Haworthian
method
Write the Fisher form of the hemiacetal form
Write the six-membered ring of epoxy in the upper right corner and number it in sequence
Write the hydroxyl groups in the Fisher formula in the corresponding numbered positions according to the "upper left, lower right" rule.
C5: D type is on the top, L type is on the bottom
nature
physics
Colorless crystal, easily soluble in water, high hydrogen bond melting and boiling point, sweet taste
Chemical
color reaction
Morich reaction (purple ring reaction)
all sugar
Concentrated sulfuric acid/concentrated hydrochloric acid Aqueous solution of sugar
Silevanov reaction
Hydrochloric acid Resorcinol
Ketose shows red color, aldose does not show color.
Anthrone reaction
Anthrone Concentrated Sulfuric Acid
blue-green
Isomerization
D-glucose can be obtained by treating D-glucose with dilute alkali to obtain D-mannose and D-fructose.
Completed by enol conversion
oxidation reaction
All monosaccharides are reducing
Check whether there are hemiacetal hydroxyl groups
Toulon's reagent, Fehling's reagent
Both aldose and ketose can be (Under alkaline conditions, the ketose group undergoes enol conversion into an aldehyde group)
Bromine water
All aldoses
Nitric acid oxidation
Dilute nitric acid oxidizes aldose to acid disaccharide ("head-to-tail")
Periodic acid oxidation
Compounds with hydroxyl or carbonyl groups on adjacent carbon atoms break the C-C bond to generate CO2 and carboxylic acid, a quantitative reaction
reduction reaction
Reduction of monosaccharides to form polyols
adult reaction
Monosaccharide phenylhydrazine-phenylhydrazone, α hydroxyl group continues to react to form uracil (yellow crystal)
Reaction site C1, C2
Ester-forming and ether-forming reactions
Esterification
Acetic anhydride
into ether
dimethyl sulfate alkaline solution
represent
249
Polysaccharide 257
starch
Straight
Branched
glycogen
Cellulose
Disaccharide 255
reducing disaccharide
maltose
Hemiacetal hydroxyl mutarotation
cellobiose
lactose
non-reducing disaccharide
sucrose
Trehalose