Basic Features

Classification

Basic concepts of polymerization thermodynamics

Heat of polymerization (enthalpy) and free energy

Polymerization heat experimental measurement method

The relationship between heat of polymerization and monomer structure

Polymerization upper limit temperature and equilibrium monomer concentration

With push electronic base

propylene monomer

With electron withdrawing group

conjugated system

elementary reaction

Type of initiator

Initiator thermal decomposition kinetics

Choice of initiator

Thermal initiation, light initiation, radiation initiation

paramagnetic resonance method

Latex particle number method

pulse laser method

Free radical lifetime measurement method

Polymerization inhibitors and inhibition mechanism

Inhibition efficiency and inhibition constant

Application of polymerization inhibitors in chain initiation rate determination

Self-blocking polymerization of allyl monomers

Degree of polymerization distribution at the end of disproportionation

Degree of polymerization distribution at termination of coupling

chain transfer constant

chain transfer reaction type

average kinetic chain length

Effect of temperature on number average degree of polymerization

Conversion rate

Microscopic kinetics of free radical polymerization

Deviation from the kinetic equations

Effect of temperature on polymerization rate

Factors affecting chain growth constant

automatic acceleration phenomenon

Conversion rate-time (C-t) curve