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MindMap Gallery Chemistry-Chapter 5 Chemical Equilibrium

Chemistry-Chapter 5 Chemical Equilibrium

An article about chemistry - Chapter 5 chemical equilibrium mind map, including equilibrium conditions of chemical reactions, gas-phase chemical reaction isotherm equations, liquid-phase chemical reaction isotherm equations, etc.

Edited at 2023-11-26 17:39:59

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Chemistry-Chapter 5 Chemical Equilibrium

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Chapter 5 Chemical Equilibrium

equilibrium conditions for chemical reactions

Determine the direction and limits of chemical reactions

The reaction proceeds spontaneously to the right

reaction reaches equilibrium

The reaction proceeds spontaneously to the left

Gas phase chemical reaction isotherm equation

van Hove isotherm equation

for ig

physical quantity that determines direction

fugacity quotient

Can be used for any gas mixture (ideal or non-ideal, because for ig, fB=PB)

The physical quantity that determines the limit

The standard molar Gibbs free energy change value of a chemical reaction is only a function of temperature.

When a chemical reaction reaches equilibrium

thermodynamic standard equilibrium constant

only a function of temperature

For complex-phase chemical reactions, only the gas phase is considered

For example, the decomposition of Ag2O

Liquid phase chemical reaction isotherm equation

Effects of temperature, pressure and inert gas on chemical equilibrium

temperature

Isobaric formula, assuming H remains constant, integrate

low pressure gas phase reaction

Isovolumetric formula

pressure

Pressurization favors volume reduction response

Inert gas

The total pressure is constant, which has the same effect as decompression

Changes in total pressure have no effect

Reactant ratio

When A and B are added in proportion to the coefficients of the reaction equation, the equilibrium content of the product will be the largest.

Calculate the standard equilibrium constant of thermodynamics

Approximately estimate the likelihood of a reaction

empirical equilibrium constant

Only related to temperature

Related to T,P

dimensionless

Description: for ig

thermodynamic standard equilibrium constant

Standard equilibrium constants for gas phase reactions

Standard equilibrium constants for liquid phase reactions

liquid mixture reaction system

solution reaction system

Standard equilibrium constants for complex phase reactions

Reactions involving gas phase and condensed phase (liquid phase, solid) are called complex-phase chemical reactions

The thermodynamic equilibrium constant and empirical equilibrium constant of a multi-phase chemical reaction are only related to the pressure of the gaseous substance and have nothing to do with the condensed phase.

dissociative pressure